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ARKIVOC Volume 2003
Part (vii): Commemorative Issue in Honor of Prof. Tony McKervey on the occasion of his 65th anniversary
Facilitator: Anita R. Maguire
Scientific Editor: Alan P. Marchand

Graphical Abstracts
1. A Tribute to Prof. M. Anthony McKervey (AM-469DT)
Anita R. Maguire
DOI: https://doi.org/10.3998/ark.5550190.0004.701
Full Text: PDF (59K)
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pp. 1 - 3
accepted Nov 8 2002; published Nov 18 2002;
2. Addition of nucleophiles to (E)-3-phenylsulfonylprop-2-enenitrile: a route to β-substituted α,β-unsaturated nitriles and to acetals of cyanoacetaldehyde (AM-595DP)
David H. Grayson and Stephen H. O’Donnell
DOI: https://doi.org/10.3998/ark.5550190.0004.702
Full Text: PDF (176K)
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pp. 4 - 14
received Oct 30 2002; accepted Dec 27 2002; published Dec 31 2002;
3. Enantioselectivity for catalytic cyclopropanation with diazomalonates (AM-666DP)
Michael P. Doyle and Wenhao Hu
DOI: https://doi.org/10.3998/ark.5550190.0004.703
Full Text: PDF (111K)
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pp. 15 - 22
received Jan 30 2003; accepted Mar 6 2003; published Mar 24 2003;
4. Important calixarene derivatives – their synthesis and applications (AM-720DR)
Gillian McMahon, Shane O’Malley, Kieran Nolan and Dermot Diamond
DOI: https://doi.org/10.3998/ark.5550190.0004.704
Full Text: PDF (195K)
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pp. 23 - 31
received Mar 5 2003; accepted Mar 24 2003; published Apr 17 2003;
5. Chemoenzymatic synthesis of enantiopure dihydroxy-1,2,3,4-tetrahydronaphthalenes (AM-707DP)
Derek R. Boyd, Narain D. Sharma, Nuala A. Kerley, Gareth McConville, Christopher C. R. Allen and A. John Blacker
DOI: https://doi.org/10.3998/ark.5550190.0004.705
Full Text: PDF (383K)
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pp. 32 - 48
received Feb 27 2003; accepted Apr 7 2003; published Apr 18 2003;
6. Enantioselective intramolecular 1,3-dipolar cycloadditions of diazocarbonyl-derived oxidopyryliums (AM-713DP)
David M. Hodgson, Paul A. Stupple and Craig Johnstone
DOI: https://doi.org/10.3998/ark.5550190.0004.706
Full Text: PDF (160K)
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pp. 49 - 58
received Feb 28 2003; accepted Apr 14 2003; published Apr 18 2003;
7. Synthesis and X-ray crystal structure of a tetracyclic gem-cis-bis(aminal) formed from N,N'-bis(2-aminophenyl)ethylenediamine and 1,10-phenanthroline-5,6-dione (AM-710DP)
Barry Coyle, Malachy McCann, Vickie McKee and Michael Devereux
DOI: https://doi.org/10.3998/ark.5550190.0004.707
Full Text: PDF (210K)
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pp. 59 - 66
received Feb 27 2003; accepted Apr 14 2003; published Apr 18 2003;
8. Sigmatropic rearrangements of 2,4-dinitrophenyl oximes (AM-721DP)
Peter H. Boyle, Haslin Dato Paduka Ali and Thomas J. Mc Donald
DOI: https://doi.org/10.3998/ark.5550190.0004.708
Full Text: PDF (232K)
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pp. 67 - 79
received Mar 5 2003; accepted Apr 14 2003; published Apr 18 2003;
9. Selectivity in cyclopropanations and 1,3-cycloadditions in transition metal-catalyzed decompositions of 2-diazocyclohexane-1,3-diones and the corresponding phenyliodonium ylides (AM-714DP)
Paul Müller, Yves F. Allenbach, Maria Ferri and Gérald Bernardinelli
DOI: https://doi.org/10.3998/ark.5550190.0004.709
Full Text: PDF (251K)
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pp. 80 - 95
received Feb 28 2003; accepted Apr 14 2003; published Apr 30 2003;
10. Chemoenzymatic methods in the asymmetric synthesis of α-diazosulfoxides (AM-695DP)
Anita R. Maguire, Stuart G. Collins and Alan Ford
DOI: https://doi.org/10.3998/ark.5550190.0004.710
Full Text: PDF (267K)
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pp. 96 - 109
received Feb 18 2003; accepted Apr 22 2003; published May 1 2003;
11. Novel cycloadducts from the 1,3-dipolar cycloaddition reactions of triazolium-1-imide 1,3-dipoles (AM-712DP)
Mairéad Sheridan, Paraic James and Cathal Healy
DOI: https://doi.org/10.3998/ark.5550190.0004.711
Full Text: PDF (120K)
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pp. 110 - 120
received Feb 28 2003; accepted Apr 22 2003; published May 3 2003;
12. New reactions of 4,5-disubstituted 1,2,3-thiadiazoles in the presence of NaH (AM-709DP)
Alan R. Katritzky, George N. Nikonov, Elizabeth L. Moyano, Novruz G. Akhmedov and Peter J. Steel
DOI: https://doi.org/10.3998/ark.5550190.0004.712
Full Text: PDF (302K)
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pp. 121 - 138
received Feb 27 2003; accepted Apr 25 2003; published May 4 2003;
13. Unprecedented regio and stereocontrol in Povarov reaction of benzylidene-(3-nitrophenyl)amine (AM-717DP)
Paul J. Stevenson and Isla Graham
DOI: https://doi.org/10.3998/ark.5550190.0004.713
Full Text: PDF (71K)
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pp. 139 - 144
received Mar 1 2003; accepted Apr 25 2003; published May 8 2003;
14. Synthesis and structure determination of three new 12β-hydroxy C20 gibberellins (GA127, GA128 and GA129) (AM-705DP)
Sarah K. Leitch, Patrick S. Blake and Lewis N. Mander
DOI: https://doi.org/10.3998/ark.5550190.0004.714
Full Text: PDF (285K)
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pp. 145 - 160
received Feb 24 2003; accepted Apr 11 2003; published May 11 2003;
15. Isoxazolo[2,3-d][1,4]benzoxazepine rings from 1,3-dipolar cycloaddition of [1,4]benzoxazepine N-oxides with acetylenic and olefinic dipolarophiles (AM-724DP)
Frances Heaney, Colm O’Mahony, Patrick McArdle and Desmond Cunningham
DOI: https://doi.org/10.3998/ark.5550190.0004.715
Full Text: PDF (377K)
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pp. 161 - 179
received Mar 7 2003; accepted May 2 2003; published May 11 2003;
16. Intermediates in the Ing-Manske reaction (AM-688DP)
O. M. Sinead Curley, Joan E. McCormick, R. Stanley McElhinney and T. Brian H. McMurry
DOI: https://doi.org/10.3998/ark.5550190.0004.716
Full Text: PDF (109K)
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pp. 180 - 189
received Feb 12 2003; accepted May 8 2003; published May 17 2003;
17. Stereoselective preparations of epoxy-, fluoro- and related derivatives of ricinoleic acid and 13(S)-hydroxyoctadeca-9(Z),11(E)-dienoic acid (AM-704DP)
Muhammad Nor Bin Omar, Richard J. Hamilton and Humphrey A. Moynihan
DOI: https://doi.org/10.3998/ark.5550190.0004.717
Full Text: PDF (123K)
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pp. 190 - 199
received Feb 24 2003; accepted May 6 2003; published May 17 2003;
18. A versatile kinetic alkylation-ozonolysis route for the synthesis of lactones: chiral γ-lactones and racemic δ-lactones (AM-715DP)
Niall W.A. Geraghty and Declan P. Costello
DOI: https://doi.org/10.3998/ark.5550190.0004.718
Full Text: PDF (329K)
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pp. 200 - 215
received Mar 3 2003; accepted May 26 2003; published May 28 2003;
19. Towards the development of controllable and reversible ‘on-off’ luminescence switching in soft-matter; synthesis and spectroscopic investigation of 1,8-naphthalimide-based PET (photoinduced electron transfer) chemosensors for pH in water-permeable hydrogels (AM-718DP)
Thorfinnur Gunnlaugsson, Colin P. McCoy, Ryan J. Morrow Caroline Phelan and Floriana Stomeo
DOI: https://doi.org/10.3998/ark.5550190.0004.719
Full Text: PDF (270K)
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pp. 216 - 228
received Mar 1 2003; accepted May 27 2003; published May 30 2003;
20. The pH-dependent fluorescence of pyridylmethyl-4-amino-1,8-naphthalimides (AM-722DP)
A. Prasanna de Silva, Anne Goligher, H.Q. Nimal Gunaratne and Terence E. Rice
DOI: https://doi.org/10.3998/ark.5550190.0004.720
Full Text: PDF (343K)
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pp. 229 - 243
received Mar 5 2003; accepted May 26 2003; published May 30 2003;
21. The reaction of unstabilised 1,3,4-oxadiazolium-N-methanide 1,3-dipoles with alkenes: N-substituted Δ-2-pyrrolines: contrast with the 1,3,4-thiadiazolium analogue (AM-647DP)
Richard N. Butler, Martin O. Cloonan, Georgina M. Smyth, Patrick McArdle and Desmond Cunningham
DOI: https://doi.org/10.3998/ark.5550190.0004.721
Full Text: PDF (207K)
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pp. 244 - 254
received Jan 10 2003; accepted May 27 2003; published Jun 5 2003;
22. Synthesis and structures of ring and cage compounds containing Si-O-As bonds (AM-728DP)
George Ferguson, Brian J. O’Leary and Trevor R. Spalding
DOI: https://doi.org/10.3998/ark.5550190.0004.722
Full Text: PDF (325K)
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pp. 255 - 267
received Mar 7 2003; accepted Jun 3 2003; published Jun 10 2003;
23. Total synthesis of cis, cis-ceratospongamide (AM-723DP)
Zhiyong Chen, Jingen Deng and Tao Ye
DOI: https://doi.org/10.3998/ark.5550190.0004.723
Full Text: PDF (308K)
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pp. 268 - 285
received Mar 5 2003; accepted Jun 4 2003; published Jun 10 2003;
24. The bromoquinone annulation reaction: a formal total synthesis of EO9 (AM-738DP)
Eamon Comer and William S. Murphy
DOI: https://doi.org/10.3998/ark.5550190.0004.724
Full Text: PDF (120K)
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pp. 286 - 296
received Mar 20 2003; accepted Jun 18 2003; published Jun 20 2003;
25. Synthesis of heterosulfamates. Search for structure-taste relationships (AM-736DP)
Wm. J. Spillane, Lorraine M. Kelly, Brendan G. Feeney, Michael G. B. Drew and Channa K. Hattotuwagama
DOI: https://doi.org/10.3998/ark.5550190.0004.725
Full Text: PDF (260K)
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pp. 297 - 309
received Mar 11 2003; accepted Jun 26 2003; published Jul 1 2003;
26. Synthesis of bicyclic lactams using novel Schmidt reactions (AM-735DP)
Mike Casey, John A. Donnelly, Joseph C. Ryan and Satoshi Ushioda
DOI: https://doi.org/10.3998/ark.5550190.0004.726
Full Text: PDF (180K)
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pp. 310 - 327
received Mar 10 2003; accepted Jun 29 2003; published Jul 3 2003;
27. Recent developments in chiral non-racemic sulfinyl group chemistry in asymmetric synthesis (AM-731DR)
Gilles Hanquet, Françoise Colobert, Steve Lanners and Guy Solladié
DOI: https://doi.org/10.3998/ark.5550190.0004.727
Full Text: PDF (729K)
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pp. 328 - 401
received Mar 7 2003; accepted Jun 26 2003; published Jul 7 2003;
28. Synthesis of mono- and diboronic acid calix[4]arene receptors (AM-739DP)
Jeremy D. Glennon, Andrew Walker and M. Anthony McKervey
DOI: https://doi.org/10.3998/ark.5550190.0004.728
Full Text: PDF (121K)
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pp. 402 - 411
received Mar 21 2003; accepted Jul 18 2003; published Jul 19 2003;
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